Bis(acetato-κ2O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
2011

Copper(II) Complex with Dimethylaminopyridine

publication Evidence: moderate

Author Information

Author(s): Benslimane Meriem, Merazig Hocine, Daran Jean-Claude

Primary Institution: Université Mentouri de Constantine

Hypothesis

The study investigates the molecular structure of a novel copper(II) complex.

Conclusion

The copper(II) complex exhibits a Jahn-Teller-distorted octahedral coordination and is stabilized by hydrogen bonds.

Supporting Evidence

  • The copper(II) ion is coordinated by two dimethylaminopyridine ligands and two acetate units.
  • The structure is stabilized by intra- and intermolecular hydrogen bonds.
  • The complex adopts a Jahn-Teller-distorted octahedral geometry.

Takeaway

Scientists created a new copper compound that has a special shape and sticks together well because of tiny connections called hydrogen bonds.

Methodology

The compound was synthesized by mixing copper acetate with dimethylaminopyridine in methanol and allowing it to crystallize.

Digital Object Identifier (DOI)

10.1107/S1600536811002017

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