Organic Papers - (Rp)-2-Isopropyl-5-methylcyclohexyl isopropyl(phenyl)phosphinate
2011
Structure of a New P-chiral Compound
publication
Evidence: moderate
Author Information
Author(s): Liu Li-Juan, Xu Hao, Meng Fan-Jie, Wang Da-Qi, Zhao Chang-Qiu
Primary Institution: Liaocheng University, Shandong, People’s Republic of China
Conclusion
The study presents the crystal structure of a new P-chiral compound with a distorted tetrahedral phosphorus atom and a stable chair conformation for the cyclohexyl ring.
Supporting Evidence
- The compound features a distorted tetrahedral phosphorus atom bonded to various groups.
- A chair conformation is observed for the cyclohexyl ring.
- Intermolecular hydrogen bonds connect molecules into a one-dimensional chain.
Takeaway
Scientists studied a new chemical compound and found that its structure has a special shape that helps it behave in a certain way.
Methodology
The compound was synthesized by reacting O-menthyl phenylphosphoryl chloride with isopropyl magnesium chloride, and its structure was determined using X-ray diffraction.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website