pH-responsive supramolecular switch of a rationally designed dipyrroethene-based chromophore
2025

pH-responsive fluorescent chromophores

publication Evidence: moderate

Author Information

Author(s): Mandal Debasish, Sarkar Abani, Behera Kanhu Charan, Ravikanth Mangalampalli

Primary Institution: Indian Institute of Technology Bombay

Hypothesis

Can we design a novel class of pH-responsive, dual-state emissive chromophores using dipyrroethenes?

Conclusion

The study successfully developed pH-responsive chromophores that exhibit reversible color changes and fluorescence in response to pH variations.

Supporting Evidence

  • The synthesized chromophores showed a large Stokes shift and maintained good fluorescence quantum yields.
  • These chromophores demonstrated reversible colorimetric changes in response to pH variations.
  • Spectroscopic techniques confirmed the structural properties and interactions of the chromophores.

Takeaway

The researchers created special color-changing materials that can glow differently depending on the acidity around them, which could be useful for sensors.

Methodology

The chromophores were synthesized through diformylation of dipyrroethenes followed by condensation with aniline derivatives, and their properties were characterized using various spectroscopic techniques.

Limitations

The study does not address the long-term stability of the chromophores in practical applications.

Digital Object Identifier (DOI)

10.1039/d4sc07016j

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