Tricyclo­hex­yl(3,5-dibromo-2-hy­droxy­benzoato-κO)tin(IV)
2011

Structure of Tricyclo­hex­yl(3,5-dibromo-2-hy­droxy­benzoato-κO)tin(IV)

publication Evidence: moderate

Author Information

Author(s): Liu Xi-Cheng, Jiang Wen-Tao, Shan Peng-Cheng, Ding Wen-Chao

Primary Institution: Qufu Normal University

Conclusion

The study describes the structure of a new organotin compound with a distorted tetrahedral geometry around the tin atom.

Supporting Evidence

  • The Sn atom in the compound exhibits a distorted tetrahedral geometry.
  • The study provides detailed bond lengths and angles around the Sn atom.
  • An intramolecular hydrogen bond was identified between the carboxyl O atom and the phenolic hydroxy group.

Takeaway

Scientists studied a new chemical compound that contains tin and found that its shape is a bit squished, like a tetrahedron that isn't quite perfect.

Methodology

The compound was synthesized by refluxing tricyclohexyltin hydroxide and 2-hydroxy-3,5-dibromobenzoic acid in toluene, followed by recrystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811020496

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