catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thiazole-κ2N,N′)cadmium]-di-μ-bromido] [CdBr2(C8H8N2S2)]
2011
Crystal Structure of a Cadmium Coordination Polymer
publication
Evidence: moderate
Author Information
Author(s): Abedi Anita, Rezaei Forugh
Primary Institution: Islamic Azad University, North Tehran Branch
Hypothesis
The study investigates the crystal structure of a cadmium coordination polymer using a specific ligand.
Conclusion
The cadmium atom in the polymer is coordinated in a distorted octahedral geometry, leading to a one-dimensional chain structure.
Supporting Evidence
- The cadmium atom is six-coordinated in a distorted octahedral geometry.
- The structure features intermolecular hydrogen bonds and π–π contacts.
- The compound was synthesized with a yield of 73.9%.
Takeaway
The researchers made a new compound with cadmium and a special molecule, and they found out how it is arranged in 3D space.
Methodology
The compound was synthesized by mixing solutions of the ligand and cadmium bromide, and suitable crystals were obtained for X-ray diffraction.
Digital Object Identifier (DOI)
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