Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)nickel(II) [Ni(NCS)2(C11H17N3)(H2O)]
2011

Study of a Nickel(II) Complex with a Schiff Base

publication Evidence: moderate

Author Information

Author(s): Suleiman Gwaram Nura, Saharin Siti Munirah, Khaledi Hamid, Mohd Ali Hapipah

Primary Institution: Department of Chemistry, University of Malaya, Kuala Lumpur, Malaysia

Hypothesis

The study investigates the structure and properties of a nickel(II) complex formed with a Schiff base and thiocyanate ions.

Conclusion

The nickel(II) complex exhibits a unique three-dimensional structure stabilized by hydrogen bonds and C—H⋯π interactions.

Supporting Evidence

  • The nickel(II) ion is coordinated by a tridentate Schiff base and two thiocyanate ions.
  • The structure features hydrogen bonds that create layers in the crystal.
  • The compound was obtained through a reflux process followed by slow evaporation.

Takeaway

The researchers created a special nickel compound that has a unique shape and is held together by tiny connections called bonds.

Methodology

The compound was synthesized by refluxing a mixture of 2-acetylpyridine, N,N-dimethylethyldiamine, nickel(II) acetate tetrahydrate, and sodium thiocyanate in ethanol.

Digital Object Identifier (DOI)

10.1107/S1600536811011512

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