Tetra­aqua­bis­(2,6-dihy­droxy­benzoato-κO1)(2,6-dihy­droxy­benzoato-κ2O1,O1′)gadolinium(III) dihydrate [Gd(C7H5O4)3(H2O)4]·2H2O
2011

Crystal Structure of Gadolinium Complex

publication Evidence: high

Author Information

Author(s): Wang Juangang, Zhang Jun, Chen Tiedan

Primary Institution: Huaibei Normal University

Conclusion

The study presents the crystal structure of a gadolinium complex with a specific coordination environment and hydrogen-bonding network.

Supporting Evidence

  • The GdIII ion shows a distorted square anti­prismatic coordination.
  • An extensive three-dimensional O—H⋯O hydrogen-bonding network consolidates the crystal packing.

Takeaway

Scientists made a special crystal with gadolinium and some other chemicals, and they found out how the atoms are arranged in it.

Methodology

The complex was synthesized by dissolving 2,6-dihydroxybenzoic acid and gadolinium nitrate in ethanol and water, respectively, followed by stirring and recrystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811016163

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