Study of a Tin Compound with Dithiocarbamate Ligand
Author Information
Author(s): Abdul Muthalib Amirah Faizah, Baba Ibrahim, Mohamed Tahir Mohamed Ibrahim, Tiekink Edward R. T.
Primary Institution: Universiti Kebangsaan Malaysia
Hypothesis
The study investigates the coordination geometry of a specific tin(IV) compound with dithiocarbamate ligands.
Conclusion
The tin(IV) atom in the compound is penta-coordinated, exhibiting a coordination geometry that is intermediate between square pyramidal and trigonal bipyramidal.
Supporting Evidence
- The SnIV atom is penta-coordinated by a dithiocarbamate ligand, a Cl atom, and two C atoms from tert-butyl groups.
- The coordination geometry is slightly closer to square pyramidal than trigonal bipyramidal.
- The study contributes to the understanding of tin dithiocarbamate compounds and their potential applications.
Takeaway
The researchers looked at a tin compound and found that it has a special shape that helps it bond with other molecules in a unique way.
Methodology
The compound was synthesized using an in situ method and characterized through X-ray crystallography.
Limitations
No specific intermolecular interactions were noted in the crystal packing.
Digital Object Identifier (DOI)
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