Bis(3,5-dimethyl-1H-pyrazole-κN2)silver(I) hexa­fluorido­anti­monate [Ag(C5H8N2)2]SbF6
2011

Structure of a Silver-Pyrazole Complex

publication Evidence: high

Author Information

Author(s): Crawford Devyn, Hofer Anthony K., Edler Kate L., Ferrence Gregory M.

Primary Institution: Department of Chemistry, Illinois State University

Conclusion

The study presents the crystal structure of a silver(I) complex with dimethylpyrazole ligands and hexa­fluorido­anti­monate anions, revealing significant hydrogen bonding and coordination interactions.

Supporting Evidence

  • The silver cation is almost linearly bonded to two nitrogen atoms of the dimethylpyrazole ligands.
  • Hydrogen bonding occurs between the dimethylpyrazole hydrogen atoms and the fluorine atoms of the hexa­fluorido­anti­monate anion.
  • The crystal structure was found to be twinned by non-merohedry.

Takeaway

Scientists studied a silver compound that has special connections with certain molecules, helping us understand how these connections work.

Methodology

The compound was synthesized in an inert atmosphere and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811010567

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