Metal-Organic Papersμ-Carbonato-bis(bis{2-[(diethylamino)methyl]phenyl}bismuth(III)) [Bi2(C11H16N)4(CO3)]
2011
Study of a New Bismuth Compound
publication
Evidence: moderate
Author Information
Author(s): Soran Albert P., Nema Mihai G., Breunig Hans J., Silvestru Cristian
Primary Institution: Facultatea de Chimie si Inginerie Chimica, Universitatea Babes-Bolyai
Conclusion
The compound exhibits a unique molecular structure with a distorted square-pyramidal coordination geometry around the bismuth atom.
Supporting Evidence
- The compound was obtained through a reaction involving sodium carbonate and diorganobismuth(III) chloride.
- X-ray crystallography revealed a distorted square-pyramidal coordination geometry around the bismuth atom.
- Intermolecular associations were observed through weak interactions leading to a ribbon-like structure.
Takeaway
Scientists created a new bismuth compound that has a special shape and structure, which helps us understand how these types of materials work.
Methodology
The compound was synthesized by reacting sodium carbonate with diorganobismuth(III) chloride in a specific solvent mixture and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
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