Di-μ-nitrito-κ4O:O-bis­[bis­(1-ethyl-1H-imidazole-κN3)(nitrito-κO)copper(II)] [Cu2(NO2)4(C5H8N2)4]
2011

Structure of a Copper Complex with Nitrite Ions

publication Evidence: moderate

Author Information

Author(s): Zhu Run-Qiang

Primary Institution: Southeast University

Hypothesis

The study aims to determine the structure of a copper complex and examine its dielectric properties.

Conclusion

The dielectric constant for the studied compound does not indicate any ferroelectric phase change between 80 K and 298 K.

Supporting Evidence

  • The compound was synthesized from an aqueous solution of 1-ethyl imidazole and copper sulfate.
  • The structure features a dimeric unit linked by hydrogen bonds.
  • The copper ion exhibits an elongated square pyramidal geometry.

Takeaway

The researchers looked at a copper compound to see if it could change its properties with temperature, but it didn't show any changes.

Methodology

The structure was determined using X-ray crystallography with a Rigaku SCXmini CCD diffractometer.

Limitations

The study did not observe any ferroelectric phase change in the temperature range tested.

Digital Object Identifier (DOI)

10.1107/S1600536811020745

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