Synthetic Efforts for Stereo Structure Determination of Cytotoxic Marine Natural Product Pericosines as Metabolites of Periconia sp. from Sea Hare
2008

Synthetic Efforts for Determining the Structure of Anticancer Compounds from Marine Sources

publication Evidence: moderate

Author Information

Author(s): Usami Yoshihide, Ichikawa Hayato, Arimoto Masao

Primary Institution: Osaka University of Pharmaceutical Sciences

Hypothesis

Can the stereo structures of pericosines, metabolites from the fungus Periconia byssoides, be determined through total synthesis?

Conclusion

Pericosines show significant cytotoxicity against leukemia cells and are promising candidates for anticancer drug development.

Supporting Evidence

  • Pericosines exhibit significant in vitro cytotoxicity against P388 lymphocytic leukemia cells.
  • Pericosine A shows the most potent activity and significant in vivo antitumor activity.
  • Total syntheses of pericosines are required to confirm their stereo structures.

Takeaway

Scientists are trying to figure out the structure of special compounds from a sea creature that can help fight cancer. They are making these compounds in the lab to understand them better.

Methodology

The review surveys synthetic efforts to produce pericosines and analogues from shikimic acid or quinic acid, including various total synthesis approaches.

Limitations

Determining the stereo structures of pericosines is challenging due to their complex multi-functionalized structures.

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