4,5-Dicarb­oxy­naphthalene-1,8-dicarb­oxy­lic anhydride–1,10-phenanthroline (1/1) C12H8N2·C14H6O7
2011

Crystal Structure of a Compound with Naphthalene and Phenanthroline

publication Evidence: moderate

Author Information

Author(s): Wu Xiang-Yang, Xu Xiang-Jun, Wang Xiang-Cheng

Primary Institution: Jiangsu University

Conclusion

The study reveals the crystal structure of a 1:1 adduct of 4,5-dicarboxynaphthalene-1,8-dicarboxylic anhydride and 1,10-phenanthroline, highlighting significant hydrogen bonding and π-π interactions.

Supporting Evidence

  • The crystal structure shows intermolecular hydrogen bonds linking molecules into dimers.
  • π-π interactions were observed between the phenanthroline and naphthalene components.
  • The study utilized a Bruker SMART CCD area-detector diffractometer for data collection.

Takeaway

The researchers looked at how two specific molecules stick together in a crystal, showing that they form strong connections with each other.

Methodology

The compound was synthesized by heating a mixture of 1,4,5,8-naphthalenetetracarboxylic acid and 1,10-phenanthroline in water under autogenous pressure.

Digital Object Identifier (DOI)

10.1107/S1600536811002492

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