1-[(Z)-1-Bromo-2-(butyl­dichloro-λ4-tellan­yl)ethen­yl]cyclo­hex-1-ene
2011

Study of a Tellurium Compound's Structure

publication Evidence: moderate

Author Information

Author(s): Zukerman-Schpector Julio, Caracelli Ignez, Guadagnin Rafael Carlos, Stefani Hélio A., Tiekink Edward R. T.

Primary Institution: Universidade Federal de São Carlos

Conclusion

The study reveals the distorted ψ-trigonal–bipyramidal geometry of the TeIV atom in the compound, influenced by various intra- and intermolecular interactions.

Supporting Evidence

  • The TeIV atom exhibits a distorted ψ-trigonal–bipyramidal geometry.
  • Close intra­molecular and inter­molecular interactions were observed.
  • Centrosymmetric dimers were formed, leading to specific crystal packing.

Takeaway

The researchers looked at a tellurium compound and found that its structure is shaped by how its atoms interact with each other.

Methodology

The compound was synthesized using a palladium-catalyzed cross-coupling reaction and characterized through X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811023142

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