(S)-2-[(2-Hy­droxy­benz­yl)aza­nium­yl]-4-(methyl­sulfan­yl)butano­ate
2011

Structural Study of a Reduced Schiff Base Derived from Methionine

publication Evidence: moderate

Author Information

Author(s): Brancatelli Giovanna, Bruno Giuseppe, Nicoló Francesco, Canfora Loredana, Ruisi Giuseppe

Primary Institution: Universitá degli Studi di Messina

Conclusion

The study successfully characterized the crystal structure of a reduced Schiff base derived from methionine, revealing its zwitterionic nature and unique hydrogen bonding interactions.

Supporting Evidence

  • The compound crystallizes in the chiral P1 space group, indicating it is a pure enantiomer.
  • An intramolecular interaction between the N—H and carboxylate groups forms a five-membered ring.
  • Hydrogen bonding interactions create a supramolecular triangle-shaped motif in the crystal.

Takeaway

The researchers looked at a special chemical compound made from methionine and found out how its atoms are arranged in a crystal, showing how they stick together.

Methodology

The compound was synthesized and then analyzed using X-ray diffraction to determine its crystal structure.

Digital Object Identifier (DOI)

10.1107/S1600536811016564

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