Androstane-3β,5α,6β,17β-tetrol tri­hydrate C19H32O4·3H2O
2011

Synthesis and Structure of Androstane-3β,5α,6β,17β-tetrol Trihydrate

publication Evidence: moderate

Author Information

Author(s): Andrade L. C. R., Almeida M. J. B. M., Paixão J. A., Carvalho J. F. S., Sá e Melo M. L.

Primary Institution: University of Coimbra

Hypothesis

The study investigates the synthesis and structural properties of a specific steroid compound.

Conclusion

The synthesized compound exhibits a unique crystal structure with extensive hydrogen bonding.

Supporting Evidence

  • The compound was synthesized by stereoselective reduction of 3β,5α,6β-trihydroxyandrostan-17-one.
  • X-ray crystallography revealed a unique hydrogen bonding network in the crystal structure.
  • Calculated molecular geometry closely matched experimental values, except for certain bond lengths.

Takeaway

Scientists made a new steroid and looked at its structure to understand how it might work in the body.

Methodology

The compound was synthesized using stereoselective reduction and characterized by X-ray crystallography.

Limitations

The absolute configuration of the molecule was not determined due to lack of strong anomalous scatterers.

Digital Object Identifier (DOI)

10.1107/S1600536811021349

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