Metal-Organic Papers
2011

Zinc Complex with Triazolopyrimidine Ligands

publication Evidence: moderate

Author Information

Author(s): Ana B. Caballero, Miguel Quirós, Antonio Rodríguez-Diéguez, Juan M. Salas

Primary Institution: Universidad de Granada

Conclusion

The study presents a zinc(II) complex with a distorted tetrahedral coordination geometry formed by specific ligands and cyanate anions.

Supporting Evidence

  • The zinc(II) ion in the complex shows a distorted tetrahedral coordination geometry.
  • Two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine ligands are coordinated through their nitrogen atoms.
  • Supra­molecular dimers are formed through stacking interactions between the ligands.

Takeaway

Scientists created a special zinc compound using two types of molecules that help it hold its shape, and they found it has a unique structure.

Methodology

The compound was synthesized by mixing aqueous solutions of zinc nitrate and sodium cyanate with a triazolopyrimidine ligand, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811005769

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