Rhenium-Sulfido and -Dithiolato Corroles: New Findings
Author Information
Author(s): Alemayehu Abraham B., Settineri Nicholas S., Lanza Arianna E., Ghosh Abhik
Primary Institution: Department of Chemistry, University of Tromsø, Norway
Hypothesis
The study investigates the synthesis and properties of rhenium-sulfido and rhenium-dithiolato corroles.
Conclusion
The study successfully synthesized rhenium-sulfido and rhenium-dithiolato corroles, demonstrating their high thermal stability and unique electronic properties.
Supporting Evidence
- The synthesis yielded rhenium-sulfido corroles in 67-76% yields.
- ReS corroles exhibited high thermal stability and reversible redox properties.
- DFT calculations indicated significant differences in electronic structure between ReS and ReO corroles.
Takeaway
Scientists created new types of rhenium compounds that are very stable and could be useful in medicine.
Methodology
The synthesis involved high-temperature reactions with free-base meso-triarylcorroles and dirhenium decacarbonyl, followed by treatment with phosphorus trichloride and thiols.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website