Water-in-bisalt electrolytes with mixed hydrophilic and hydrophobic anions for enhanced transport and stability for potassium-ion batteries
2025

Enhanced Potassium-Ion Battery Electrolytes

publication Evidence: high

Author Information

Author(s): Dhasarathaboopathy Mukhilan, Sabhapathy Palani, Gurkan Burcu

Primary Institution: Department of Chemical and Biomolecular Engineering, Case Western Reserve University

Hypothesis

Can a binary salt approach improve the transport and stability of potassium-ion battery electrolytes?

Conclusion

The study demonstrates that a mixed bi-salt approach in water-in-salt electrolytes can significantly enhance the transport properties and electrochemical stability for potassium batteries.

Supporting Evidence

  • The mixed bi-salt approach achieved a high K+ concentration of 36 molal.
  • The ionic conductivity of the new electrolyte was measured at 18 mS cm−1 at 25 °C.
  • The electrochemical stability window exceeded 4.74 V.

Takeaway

This study found a way to make better battery juice for potassium batteries by mixing two types of salts, which helps the battery work better and last longer.

Methodology

The study involved creating a eutectic mixture of potassium acetate and potassium trifluoromethane sulfonate salts and analyzing its properties using Raman and NMR spectroscopy.

Digital Object Identifier (DOI)

10.1039/d4ra08378d

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