Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nona­hydrate
2011

Structure of a New Compound with Tartaric Acid and Phenanthroline

publication Evidence: moderate

Author Information

Author(s): Z. Derikvand, M. M. Olmstead

Primary Institution: Islamic Azad University, Khorramabad Branch, Iran; University of California, Davis, USA

Conclusion

The study reveals a complex crystal structure involving hydrogen bonding interactions between tartrate anions and phenanthroline cations.

Supporting Evidence

  • The crystal structure contains two cations and two anions along with nine water molecules.
  • Hydrogen bonding interactions play a significant role in stabilizing the crystal structure.
  • Short hydrogen bonds were observed between adjacent tartrate anions.

Takeaway

Scientists created a new crystal by mixing tartaric acid and phenanthroline, which formed a structure with lots of tiny connections holding it together.

Methodology

The compound was synthesized by mixing aqueous D-tartaric acid with 2,9-dimethyl-1,10-phenanthroline in a 1:1 molar ratio and allowing the solution to evaporate slowly.

Digital Object Identifier (DOI)

10.1107/S160053681005110X

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