Aqua­[N′-(3-eth­oxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2N′,O]dioxido­molybdenum(VI)–4,4′-bipyridine (2/1) [Mo(C14H12N2O4)O2(H2O)]·0.5C10H8N2
2011

Study of a New Molybdenum Complex with Schiff Base

publication Evidence: moderate

Author Information

Author(s): Ngan Ngui Khiong, Wong Richard Chee Seng, Lo Kong Mun, Ng Seik Weng

Primary Institution: University of Malaya

Conclusion

The study presents a new dioxido­molybdenum(VI) complex that exhibits unique structural features and coordination modes.

Supporting Evidence

  • The new complex features a unique octahedral geometry.
  • The five-membered chelate ring is planar while the six-membered ring is puckered.
  • Hydrogen bonds link the molecules into a linear chain structure.

Takeaway

Researchers created a new chemical compound using molybdenum and a special type of organic molecule, which has interesting shapes and connections.

Methodology

The compound was synthesized by condensing specific organic compounds in methanol and then crystallizing the resulting mixture.

Digital Object Identifier (DOI)

10.1107/S1600536811017260

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