Benzyltriphenylphosphonium perchlorate
2011
Crystal Structure of Benzyltriphenylphosphonium Perchlorate
publication
Evidence: moderate
Author Information
Author(s): Li Liwei, He Xiaoqiang
Primary Institution: College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, Hubei, People’s Republic of China
Conclusion
The study presents the crystal structure of benzyltriphenylphosphonium perchlorate, revealing its unique molecular interactions.
Supporting Evidence
- The asymmetric unit contains two independent cations and two independent anions.
- The closest intermolecular contact is a weak C—H···π(arene) interaction.
- The P atoms are bonded in slightly distorted tetrahedral environments.
Takeaway
This study shows what benzyltriphenylphosphonium perchlorate looks like at a tiny level, helping us understand how its parts fit together.
Methodology
The compound was synthesized by reacting [Ph3(PhCH2)]Cl and NaClO4.H2O in ethanol, followed by crystallization.
Digital Object Identifier (DOI)
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