Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4 N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate
2011
Iron(III) Porphyrin Complex Structure
publication
Evidence: high
Author Information
Author(s): Dhifet Mondher, Belkhiria Mohamed Salah, Daran Jean-Claude, Nasri Habib
Primary Institution: Université de Monastir
Conclusion
The study presents the crystal structure of a specific iron(III) porphyrin complex, highlighting its unique coordination and geometry.
Supporting Evidence
- The iron atom is displaced by 0.420 Å from the mean plane of the porphyrin core.
- The equatorial iron–pyrrole N atom distance is 2.065 Å.
- The axial Fe–Cl distance is 2.207 Å.
Takeaway
Scientists studied a special iron molecule that is part of a larger structure, showing how it connects with other atoms in a specific way.
Methodology
The crystal structure was determined using X-ray diffraction techniques.
Limitations
The solvent molecules were disordered and excluded from the refinement.
Digital Object Identifier (DOI)
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