Sodium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
2011
Structure of Sodium N-bromo-2-chlorobenzenesulfonamidate
publication
Evidence: moderate
Author Information
Author(s): Gowda B. Thimme, Foro Sabine, Shakuntala K.
Primary Institution: Mangalore University
Hypothesis
The study explores the effects of substituents on the crystal structures of N-haloarylsulfonamides.
Conclusion
The crystal structure of sodium N-bromo-2-chlorobenzenesulfonamidate is stabilized by hydrogen bonds and shows a pseudo-octahedral coordination of the sodium ion.
Supporting Evidence
- The sodium ion shows pseudo-octahedral coordination with three water molecules and three sulfonyl oxygen atoms.
- The S—N distance of 1.579 Å indicates a double bond character.
- The crystal structure is stabilized by multiple hydrogen bonds.
Takeaway
This study looks at how different chemical groups affect the structure of a specific compound, helping us understand its properties better.
Methodology
The compound was prepared using a literature method, characterized by infrared and NMR spectra, and analyzed using X-ray diffraction.
Digital Object Identifier (DOI)
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