Metal-Organic Papers(η3-Allyl)bromido(1-phenyl-1H-imidazole-κN3)palladium(II) [PdBr(C3H5)(C9H8N2)]
2011
Crystal Structure of a Palladium Complex
publication
Evidence: moderate
Author Information
Author(s): Huang Jiangying, Zhang Xiao
Primary Institution: Zhejiang Gongshang University
Conclusion
The study successfully synthesized and characterized a palladium complex with specific ligand interactions.
Supporting Evidence
- The palladium atom is coordinated by one allyl group, one bromide anion, and a 1-phenyl-1H-imidazole ligand.
- Intramolecular face-to-face π–π stacking interactions occur between adjacent phenyl or imidazole groups.
- Colorless crystals were obtained by vapor diffusion of hexane into an ethyl acetate solution.
Takeaway
Scientists made a new compound using palladium and studied its structure to understand how it works.
Methodology
The compound was synthesized by reacting allylpalladium(II) bromide dimer with 1-phenyl-1H-imidazole in THF, followed by purification and crystallization.
Digital Object Identifier (DOI)
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