Tetra­aqua­bis­[2-(2-oxo-2,3-dihydro-1,3-benzoxazol-3-yl)acetato]­zinc [Zn(C9H6NO4)2(H2O)4]
2011

Zinc Complex with Water Molecules

publication Evidence: moderate

Author Information

Author(s): Ashurov Jamshid, Karimova Gavhar, Mukhamedov Nasir, Parpiev Nusrat A., Ibragimov Bakhtijar

Primary Institution: Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan

Conclusion

The study reveals the crystal structure of a zinc complex that is octahedrally coordinated by water molecules and ligands, forming hydrogen-bonded sheets.

Supporting Evidence

  • The zinc ion is located on an inversion center and is octahedrally coordinated.
  • The structure features strong hydrogen bonds between water molecules and ligand oxygen atoms.
  • Pleated sheets are formed in the crystal structure due to hydrogen bonding.

Takeaway

Scientists studied a zinc compound that has water molecules attached to it, and they found that these molecules help form a special structure.

Methodology

The compound was synthesized by mixing 2-benzoxazolinon-3-yl-acetate acid with zinc chloride in ethanol and water, followed by slow evaporation to obtain crystals for X-ray analysis.

Digital Object Identifier (DOI)

10.1107/S1600536811007999

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