7,7′-Dihydroxy-4,4′-dimethyl-3,4-dihydro-2H,2′H-4,6′-bichromene-2,2′-dione
2011
Synthesis and Structure of a Novel Coumarin Dimer
publication
Evidence: moderate
Author Information
Author(s): Pereira Silva P. S., Parveen Mehtab, Ali Akhtar, Malla Ali Mohammed, Ramos Silva M.
Primary Institution: University of Coimbra
Hypothesis
The study investigates the synthesis and crystal structure of a novel coumarin dimer.
Conclusion
The synthesized coumarin dimer crystallizes as a racemate and forms a three-dimensional network through hydrogen bonding.
Supporting Evidence
- The title compound contains one chiral center and crystallizes as a racemate.
- The mean planes of the two coumarin units make a dihedral angle of 88.07°.
- The structure is stabilized by O—H···O hydrogen bonds forming a three-dimensional network.
Takeaway
Scientists made a new type of coumarin, which is a special kind of chemical, and found out how it looks when it's all put together.
Methodology
The coumarin dimer was synthesized using resorcinol and ethyl acetoacetate with a catalytic amount of polyphosphoric acid.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website