Atomistic Origins of Conductance Switching in an ε-Cu0.9V2O5 Neuromorphic Single Crystal Oscillator
2024

Understanding Conductance Switching in a Neuromorphic Material

publication Evidence: high

Author Information

Author(s): Ponis John, Jerla Nicholas, Agbeworvi George, Perez-Beltran Saul, Kumar Nitin, Ashen Kenna, Li Jialu, Wang Edrick, Smeaton Michelle A., Jardali Fatme, Chakraborty Sarbajeet, Shamberger Patrick J., Jungjohann Katherine L., Weiland Conan, Jaye Cherno, Ma Lu, Fischer Daniel, Guo Jinghua, Sambandamurthy G., Qian Xiaofeng, Banerjee Sarbajit

Primary Institution: Texas A&M University

Hypothesis

What are the atomic origins of conductance switching in ε-Cu0.9V2O5?

Conclusion

The study reveals that conductance switching in ε-Cu0.9V2O5 is driven by the mobility of Cu ions and their interactions with the vanadium oxide framework.

Supporting Evidence

  • Conductance switching was observed to span almost 2 orders of magnitude at around 146 K.
  • Single-crystal X-ray diffraction revealed superlattice ordering of Cu ions at low temperatures.
  • X-ray absorption and emission spectroscopies showed that Cu 3d and V 3d orbitals overlap near the Fermi level.

Takeaway

This research shows how tiny changes in the arrangement of atoms in a material can help create better computer circuits that work like the human brain.

Methodology

The study used single-crystal X-ray diffraction, X-ray absorption and emission spectroscopies, and molecular dynamics simulations to analyze the material.

Limitations

The study may not account for all variations in compositions and defect concentrations across different samples.

Digital Object Identifier (DOI)

10.1021/jacs.4c11968

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