Bis(μ-adamantane-1,3-dicarboxyl­ato-κ4O1,O1′:O3,O3′)bis­[aqua­(3-carboxy­adam­ant­ane-1-carboxyl­ato-κO1)(1,10-phen­an­throline-κ2N,N′)erbium(III)] dihydrate [Er2(C12H14O4)2(C12H15O4)2(C12H8N2)2(H2O)2]·2H2O
2011

Crystal Structure of a Lanthanide Complex

publication Evidence: moderate

Author Information

Author(s): Zhu Hong-lin, Huang Wen-xiang, Chang Hai-sheng

Primary Institution: Ningbo University

Conclusion

The study presents the crystal structure of a lanthanide complex that exhibits extensive hydrogen-bonding and π–π interactions.

Supporting Evidence

  • The compound contains one ErIII atom and various ligands.
  • Extensive hydrogen-bonding interactions lead to the formation of chains.
  • Chains are linked into a layer-like network by π–π stacking interactions.

Takeaway

Scientists studied a special compound made of lanthanide ions and certain organic molecules, and they found that these parts stick together in interesting ways.

Methodology

The compound was synthesized through a reaction involving Er2O3 and 1,3-adamantanedicarboxylic acid, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811023075

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