Metal-Organic Papers
2011
New Platinum Complex with a Thiolate-Carboxylate Ring
publication
Evidence: moderate
Author Information
Author(s): Matthew S. McCready, Richard J. Puddephatt
Primary Institution: University of Western Ontario
Hypothesis
The oxidative addition of a disulfide to a platinum(II) complex can lead to the formation of a thiolate-carboxylate chelate ring.
Conclusion
The study presents a new platinum(IV) complex that features an unusual thiolate-carboxylate chelate ring formed through oxidative addition.
Supporting Evidence
- The complex exhibits a slightly distorted octahedral geometry.
- The formation of the thiolate-carboxylate chelate ring is a novel observation for platinum(IV).
- The study highlights the potential applications of disulfides in catalysis.
Takeaway
Scientists created a new type of platinum compound that has a special ring structure, which could be useful in medicine and chemistry.
Methodology
The complex was synthesized through the oxidative addition of a disulfide to a platinum(II) precursor, followed by crystallization.
Digital Object Identifier (DOI)
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