Determination of Zinc-Based Additives in Lubricating Oils by Flow-Injection Analysis with Flame-AAS Detection Exploiting Injection with a Computer-Controlled Syringe
2005

Automated Analysis of Zinc in Lubricating Oils

publication Evidence: moderate

Author Information

Author(s): Gustavo Pignalosa, Moisés Knochen, Noel Cabrera

Primary Institution: Facultad de Química, Universidad de la República

Hypothesis

Can flow-injection analysis with syringe injection improve the determination of zinc-based additives in lubricating oils?

Conclusion

The automated method using a motorised syringe for sample injection effectively determines zinc in lubricating oils with results comparable to standard methods.

Supporting Evidence

  • The method showed no significant differences compared to the ASTM method at the 95% confidence level.
  • Precision was better than 5% for high concentrations and typically 2%.
  • The system achieved a sampling frequency of about 30 samples per hour.

Takeaway

This study shows a new way to test oil for zinc using a special machine that makes it easier and faster to get accurate results.

Methodology

The study used a flow-injection system with a motorised syringe to inject oil samples into a kerosene stream for analysis by atomic absorption spectrometry.

Limitations

The method may have limitations in precision at low concentrations due to the nature of the samples.

Statistical Information

P-Value

p<0.05

Confidence Interval

95%

Statistical Significance

p<0.05

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