Bis(1,3-dimethyl-1,3-diazinan-2-one)dinitratodioxidouranium(VI) [U(NO3)2O2(C6H12N2O)2]
2011

New Uranium Complex with DMPU

publication Evidence: moderate

Author Information

Author(s): Suzuki Tomoya, Kawasaki Takeshi, Ikeda Yasuhisa

Primary Institution: Tokyo Institute of Technology

Hypothesis

The study investigates the synthesis and crystal characterization of a new uranyl(VI) complex, UO2(NO3)2(DMPU)2.

Conclusion

The new uranyl(VI) complex exhibits a hexagonal bipyramidal geometry and specific bond lengths that differ from other known complexes.

Supporting Evidence

  • The complex was characterized using X-ray crystallography.
  • The geometry of the complex is hexagonal bipyramidal.
  • The study provides detailed bond lengths and angles for the new compound.

Takeaway

Scientists created a new type of uranium compound and found that its shape and structure are a bit different from similar compounds.

Methodology

The compound was synthesized by mixing uranyl stock solution with DMPU and filtering the resulting precipitate.

Digital Object Identifier (DOI)

10.1107/S1600536810049883

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