Metal-Organic Papers
2011

Crystal Structure of a Tetra-Nuclear Organotin Complex

publication Evidence: moderate

Author Information

Author(s): Yupo Ren

Primary Institution: Liaocheng People’s Hospital

Hypothesis

The study investigates the crystal structure of a new organotin compound.

Conclusion

The synthesized organotin compound exhibits a tetra-nuclear structure with distinct coordination geometries.

Supporting Evidence

  • The compound has crystallographically imposed inversion symmetry.
  • The coordination polyhedron around the central tin atoms is distorted trigonal-bipyramidal.
  • The peripheral tin atoms exhibit distorted octahedral coordination geometry.
  • The crystal structure features long Sn⋯O contacts forming chains along the [011] direction.

Takeaway

Scientists made a new type of tin compound and looked at its structure using X-ray analysis. They found it has a special shape with four tin atoms connected together.

Methodology

The compound was synthesized under nitrogen atmosphere and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811023452

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