Dinitrosylbis[tris(4-chlorophenyl)phosphane]iron [Fe(NO)2(C18H12Cl3P)2]
2011

Dinitrosyl Iron Diphosphane Complex

publication Evidence: moderate

Author Information

Author(s): Myron W. Jones, Douglas R. Powell, George B. Richter-Addo

Primary Institution: University of Oklahoma

Conclusion

The study presents the crystal structure of a dinitrosyl iron diphosphane complex, revealing its tetrahedral geometry and specific bond angles.

Supporting Evidence

  • The iron atom in the complex is tetrahedrally coordinated by two phosphane ligands and two nitrosyl groups.
  • The study utilized X-ray diffraction to determine the molecular structure.
  • The isolated yield of the compound was 33%.

Takeaway

Scientists created a new chemical compound that has a special shape, and they figured out how its atoms are arranged.

Methodology

The compound was synthesized from a toluene solution and characterized using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811001693

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