Hexa-μ2-chlorido-μ4-oxido-tetra­kis­[(3-methyl-5-phenyl-1H-pyrazole-κN2)copper(II)] [Cu4Cl6O(C10H10N2)4]
2011

New Copper Complex with Chloride and Pyrazole Ligands

publication Evidence: moderate

Author Information

Author(s): He Hongshan

Primary Institution: South Dakota State University

Hypothesis

The study investigates the formation of a new copper complex when 5-methyl-3-phenylpyrazole reacts with copper chloride.

Conclusion

The new copper complex features a unique structure with four copper atoms bridged by six chloride ions and coordinated by pyrazole ligands.

Supporting Evidence

  • The compound contains four CuII atoms bridged by six chloride anions.
  • Each CuII atom is coordinated by a pyrazole ligand and chloride ions.
  • The geometry around each CuII atom is distorted trigonal–bipyramidal.

Takeaway

Scientists created a new type of copper compound using special chemicals, and it has a unique shape that helps hold the copper atoms together.

Methodology

The compound was synthesized by dissolving 5-methyl-3-phenylpyrazole in dichloromethane and adding copper(II) chloride dihydrate, followed by filtration and crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810053663

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