Metal-Organic Papers(μ-2,3-Dibromo­succinato-κ2 O1:O4)bis­[methano­lato-κO)triphenyl­anti­mony(V)] [Sb2(C6H5)6(C4H2Br2O4)(CH3O)2]
2011

Study of a Dinuclear Antimony Compound

publication

Author Information

Author(s): Quan Li, Yin Handong, Fu Wenfu

Primary Institution: Chinese Academy of Sciences

Conclusion

The study presents the synthesis and structural characteristics of a dinuclear antimony compound linked by a dibromosuccinate ligand.

Supporting Evidence

  • The compound features a dinuclear structure with a bridging ligand.
  • The antimony atom is five-coordinated in a distorted trigonal-bipyramidal geometry.
  • C—H⋯O interactions create a two-dimensional network in the solid state.

Takeaway

Scientists made a new compound using antimony and studied its structure. They found it has a special shape and connects in a unique way.

Methodology

The compound was synthesized by refluxing 2,3-dibromosuccinic acid with sodium methoxide and triphenylantimony chloride in methanol.

Digital Object Identifier (DOI)

10.1107/S1600536811016114

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