N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) [Mo(C14H9ClN2O4)O2(CH4O)]·C10H8N2
2011
New Metal-Organic Compound with Schiff Base
publication
Evidence: moderate
Author Information
Author(s): Ngan Ngui Khiong, Wong Richard Chee Seng, Lo Kong Mun, Ng Seik Weng
Primary Institution: University of Malaya
Conclusion
The study presents a new co-crystal structure involving a Schiff base and dioxomolybdenum(VI) that forms hydrogen bonds leading to a helical chain.
Supporting Evidence
- The new compound features a Schiff base that coordinates with a molybdenum atom.
- Hydrogen bonds in the structure create a helical chain along the b-axis.
- The study utilized advanced crystallographic techniques to determine the structure.
Takeaway
Scientists created a new compound using a special chemical that helps metals bond in a unique way, forming a spiral structure.
Methodology
The compound was synthesized by condensing 3-ethoxysalicylaldehyde with 2,4-dihydroxybenzohydrazide in methanol, followed by the addition of dioxomolybdenum(VI) and 4,4'-bipyridine.
Digital Object Identifier (DOI)
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