Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)cerium(III) [Ce(C7H5O3)2(NO3)(C12H8N2)2]
2011

Structure of a Cerium(III) Complex

publication Evidence: high

Author Information

Author(s): Gu Xiaojian, Wang Chiya, Hong Bo, Jin Hongxiao

Primary Institution: College of Materials Science and Engineering, China Jiliang University

Conclusion

The study presents the crystal structure of a cerium(III) complex with specific geometric and bonding characteristics.

Supporting Evidence

  • The cerium complex exhibits a pseudo-bicapped square-antiprismatic geometry.
  • π–π stacking interactions stabilize the crystal structure.
  • Intra­molecular O—H⋯O hydrogen bonds are present in the ligands.

Takeaway

Scientists studied a special cerium compound to see how its atoms are arranged, and they found it has a unique shape.

Methodology

The crystal structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536810049755

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