Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide-κO)tin(II)] [Sn2Cl4(C2H6OS)4]
2011

Structure of a Tin(II) Compound

publication Evidence: high

Author Information

Author(s): Barbul Ioana, Varga Richard A., Silvestru Cristian

Primary Institution: Babes-Bolyai University

Hypothesis

The study investigates the structure of the compound [Sn2Cl4(C2H6OS)4] formed during the reaction of SnCl2 with an organic halide.

Conclusion

The compound features dimers with a planar Sn2Cl2 core and a distorted octahedral coordination geometry around the tin atoms.

Supporting Evidence

  • The compound was isolated as a by-product of a reaction involving SnCl2.
  • The structure contains dimers connected through weak Sn⋯Cl interactions.
  • Tin atoms in the compound exhibit a distorted octahedral coordination geometry.

Takeaway

Scientists studied a tin compound that forms pairs of molecules, showing how the tin is connected to chlorine and oxygen atoms.

Methodology

The structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536811009895

Want to read the original?

Access the complete publication on the publisher's website

View Original Publication