2-[1-(3-Amino­phenyl­imino)­eth­yl]phenol C14H14N2O
2011

Study of a New Ketimine Schiff Base

publication Evidence: moderate

Author Information

Author(s): Anita Blagus, Branko Kaitner

Primary Institution: Department of Chemistry, J. J. Strossmayer University, Osijek

Hypothesis

The molecular conformation of the compound in the crystalline state is in the enol-imino form.

Conclusion

The study successfully characterized the crystal and molecular structure of a novel ketimine Schiff base.

Supporting Evidence

  • The compound exists as the enol–imine tautomer.
  • A strong intramolecular hydrogen bond forms a six-membered ring.
  • Intermolecular hydrogen bonds link the molecules into infinite chains.

Takeaway

Scientists made a new chemical compound and looked at its structure to understand how it works.

Methodology

The compound was prepared by refluxing a solution of m-phenylenediamine and 2-hydroxyacetophenone, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811017624

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