Diaquabis[5-(2-pyridylmethyl)tetrazolato-κ2N1,N5]zinc(II) [Zn(C7H6N5)2(H2O)2]
2011
Crystal Structure of a Zinc(II) Complex with Tetrazolate Ligands
publication
Evidence: moderate
Author Information
Author(s): Liu Yang, Li Ya-Ling, Wang Xiu-Guang, Yang En-Cui
Primary Institution: Tianjin Normal University
Hypothesis
The study investigates the crystal structure of a diaquazinc(II) complex with an in situ generated 5-(2-pyridylmethyl)-tetrazolate ligand.
Conclusion
The zinc(II) complex exhibits a distorted octahedral geometry and forms a three-dimensional network through hydrogen bonding.
Supporting Evidence
- The zinc(II) ion is coordinated by two tetrazolate ligands and two water molecules.
- The structure features intermolecular hydrogen bonds that create a three-dimensional network.
- The synthesis method is noted for its effectiveness and environmental friendliness.
Takeaway
Scientists created a special zinc compound that has a unique shape and sticks together in a cool way, like building blocks.
Methodology
The compound was synthesized by heating a mixture of specific chemicals in a sealed reactor, followed by X-ray diffraction analysis of the resulting crystals.
Digital Object Identifier (DOI)
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