Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)manganese(II) [Mn(NCS)2(C13H19N3O)(H2O)]
2011

Study of a Manganese(II) Complex with a Schiff Base Ligand

publication Evidence: moderate

Author Information

Author(s): Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah

Primary Institution: Department of Chemistry, University of Malaya

Conclusion

The study successfully characterized a manganese(II) complex with a Schiff base ligand, revealing its distorted octahedral geometry and hydrogen bonding interactions.

Supporting Evidence

  • The manganese(II) complex was characterized using X-ray crystallography.
  • The structure features a distorted octahedral geometry around the manganese atom.
  • Hydrogen bonding interactions were observed in the crystal structure.

Takeaway

Scientists made a special manganese compound and looked at how its atoms are arranged. They found that it has a unique shape and sticks together in interesting ways.

Methodology

The compound was synthesized by refluxing a mixture of 2-acetylpyridine and 4-(2-aminoethyl)morpholine, followed by the addition of manganese(II) acetate and ammonium thiocyanate.

Digital Object Identifier (DOI)

10.1107/S1600536811022124

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