Bis(μ-N,N′,N′′-tri-3-pyridylpyridine-1,3,5-tricarboxamide-κ2N:N′)bis­[di­chloridomercury(II)] methanol disolvate [Hg2Cl4(C24H18N6O3)2]·2CH4O
2011

New Mercury Coordination Complex

publication Evidence: moderate

Author Information

Author(s): Wang Pei, Wang Yufei, Huang Chao, Chang Lixiang, Wu Jie

Primary Institution: Zhengzhou University

Conclusion

The study reports the synthesis and characterization of a new dinuclear mercury coordination complex with specific geometric and bonding properties.

Supporting Evidence

  • The compound features mercury atoms coordinated by chlorine and nitrogen atoms.
  • The structure exhibits a distorted tetrahedral geometry.
  • Intermolecular hydrogen bonds contribute to the three-dimensional network of the crystal.

Takeaway

Scientists made a new compound using mercury and special ligands, which helps in understanding how these materials can be structured.

Methodology

The ligand was added to a solution of mercury chloride, and the resulting mixture was allowed to stand to form crystals.

Digital Object Identifier (DOI)

10.1107/S160053681102040X

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