Cs0.49NbPS6
2011

Synthesis and Structure of Cs0.49NbPS6

publication Evidence: moderate

Author Information

Author(s): Lee Eunsil, Lee Yonghee, Yun Hoseop

Primary Institution: Ajou University

Hypothesis

The study aims to synthesize and characterize a new quaternary thiophosphate compound, Cs0.49NbPS6.

Conclusion

The compound Cs0.49NbPS6 has been successfully synthesized and characterized, revealing a unique three-dimensional network structure.

Supporting Evidence

  • The compound is isotypic with Rb0.46TaPS6.
  • The structure consists of a bicapped trigonal biprismatic [Nb2S12] unit and a tetrahedral [PS4] group.
  • The synthesis involved a reaction of Nb, P, and S in a specific molar ratio.

Takeaway

Scientists made a new material called Cs0.49NbPS6, which has a special structure that helps it hold together well.

Methodology

The compound was synthesized using the reactive halide flux method with elements Nb, P, and S.

Digital Object Identifier (DOI)

10.1107/S1600536810052724

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