Quaternary Mixed Oxides of Non-Noble Metals with Enhanced Stability during the Oxygen Evolution Reaction
2024

New Non-Noble Metal Oxides for Hydrogen Production

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Author Information

Author(s): Piñeiro-García Alexis, Wu Xiuyu, Canto-Aguilar Esdras J., Kuzhikandathil Alice, Rafei Mouna, Gracia-Espino Eduardo

Primary Institution: Umeå University

Hypothesis

Can quaternary mixed oxides based on non-noble metals enhance stability during the oxygen evolution reaction?

Conclusion

The new family of quaternary mixed oxides shows enhanced stability and potential for use in sustainable hydrogen production.

Supporting Evidence

  • The mixed oxides exhibit enhanced stability in both acidic and alkaline environments under anodic potentials.
  • Co- and Mn-based mixed oxides show significant activity toward the oxygen evolution reaction.
  • The incorporation of oxidizing agents was crucial for the formation of the rutile structure.
  • Electrochemical tests demonstrated minimal degradation of the mixed oxides after extensive cycling.
  • XPS analysis confirmed the presence of various oxidation states in the mixed oxides.

Takeaway

Scientists created new materials that help produce hydrogen from water without using expensive metals, and these materials are very stable.

Methodology

The mixed oxides were produced using solution precursor plasma spraying and characterized through various techniques including XRD and electrochemical measurements.

Limitations

The study primarily focuses on the stability and activity of the mixed oxides without extensive exploration of their long-term performance in practical applications.

Digital Object Identifier (DOI)

10.1021/acsami.4c10234

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