Dibromidobis[1-(2,4,6-trimethylphenyl)-1,4,5,6-tetrahydropyrimidine-κN3]palladium(II) [PdBr2(C13H18N2)2]
2011
New Palladium Complex with Tetrahydropyrimidine Ligand
publication
Evidence: moderate
Author Information
Author(s): Mao Pu, Liu Xiujun, Yang Liangru, Yuan Jinwei, Song Maoping
Primary Institution: Zhengzhou University
Hypothesis
The reaction of a tetrahydropyrimidine salt with Pd(OAc)2 will yield a new palladium complex.
Conclusion
The study successfully synthesized a new palladium complex with a unique structural configuration.
Supporting Evidence
- The palladium atom is located at an inversion center.
- The organic ligands twist away from the coordination plane.
- The yield of the synthesized compound was 66%.
Takeaway
Scientists made a new compound using palladium and a special chemical, and it has a unique shape.
Methodology
The palladium complex was synthesized by reacting Pd(OAc)2 with a tetrahydropyrimidine ligand in DMSO, followed by crystallization.
Digital Object Identifier (DOI)
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