Tris(piperazine-1,4-diium) bis­[hexa­chloridoindate(III)] tetra­hydrate (C4H12N2)3[InCl6]2·4H2O
2011

New Hybrid Compound with Piperazine and Indate

publication

Author Information

Author(s): Bouacida Sofiane, Belhouas Ratiba, Fantazi Boubakeur, Boudaren Chaouki, Roisnel Thierry

Primary Institution: Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Université Mentouri-Constantine

Conclusion

The study presents the synthesis and crystal structure of a new hybrid compound consisting of piperazinium cations and hexachloridoindate anions.

Supporting Evidence

  • The asymmetric unit consists of piperazinium cations, hexachloridoindate anions, and water molecules.
  • The InIII ion is six-coordinated in a quasi-regular octahedral arrangement.
  • The crystal structure features a complex three-dimensional network stabilized by hydrogen bonds.

Takeaway

Scientists made a new type of crystal using special chemicals, and they found out how it looks at a tiny level.

Methodology

The compound was synthesized by evaporating a solution of InCl3 and piperazine in hydrochloric acid over a week.

Digital Object Identifier (DOI)

10.1107/S1600536811007355

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