Poly[tetrakis(μ4-4,6-dimethyl-5-nitrobenzene-1,3-dicarboxylato-κ2O1:O1′:O3:O3′)bis(pyridine-κN)dizinc]
2011
New Zinc Complex Structure
publication
Evidence: moderate
Author Information
Author(s): Ma Qing-Yu, Guan Rui-Fang, Li Guo-Zhong
Primary Institution: School of Materials Science and Engineering, University of Jinan, Jinan, People’s Republic of China
Hypothesis
The study investigates the structure of a new zinc complex formed from specific ligands.
Conclusion
The complex forms a two-dimensional polymeric structure with specific coordination geometry around the zinc atoms.
Supporting Evidence
- The complex is a centrosymmetric tetra-carboxylato-bridged dimer.
- Each zinc atom is five-coordinated by four oxygen atoms and one nitrogen atom.
Takeaway
Scientists created a new zinc compound that has a special structure, which could be useful for making new materials.
Methodology
The compound was synthesized by reacting 4,6-dimethyl-5-nitroisophthalic acid with Zn(NO3)2 in a mixed solvent and heating the solution.
Digital Object Identifier (DOI)
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