3,4-Bis(4-bromo­phen­yl)-N-phenyl­maleimide
2011

Structure of 3,4-Bis(4-bromophenyl)-N-phenylmaleimide

publication Evidence: moderate

Author Information

Author(s): Liu Yong, Zheng Shuai, Zhou Jing, Gao Dongmei, Du Zhen-Ting

Primary Institution: Northwest University for Nationalities

Conclusion

The study reports the crystal structure of 3,4-bis(4-bromophenyl)-N-phenylmaleimide, revealing significant conjugation between the benzene and maleimide units.

Supporting Evidence

  • The molecule has a propeller-like arrangement of three benzene rings around a central maleimide ring.
  • The C—C bond lengths connecting the benzene groups and maleimide are shorter than typical single bonds, indicating partial conjugation.
  • A weak non-classical hydrogen bond stabilizes the crystal structure.

Takeaway

The researchers looked at a special molecule with rings that are arranged in a unique way, showing that parts of it are connected more strongly than usual.

Methodology

The crystal structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536811014152

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