Metal-Organic Papers[1,2-Bis(diphenyl­phosphan­yl)ethane-κ2 P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ2 C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
2011

Crystal Structure of a Palladium Complex

publication Evidence: high

Author Information

Author(s): Rizzoli Corrado, Karami Kazem, Borzooie Farzaneh

Primary Institution: Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Universitá degli Studi di Parma

Conclusion

The study presents the synthesis and crystal structure of a palladium(II) complex with a tetrahedrally distorted square-planar coordination geometry.

Supporting Evidence

  • The palladium(II) atom shows a slightly distorted square-planar coordination.
  • Intermolecular hydrogen bonds link cations and anions into a three-dimensional network.
  • The study contributes to the understanding of cyclopalladated metal complexes.

Takeaway

Scientists made a special metal compound and looked at its structure using X-ray. They found it has a unique shape that could help in making new materials.

Methodology

The compound was synthesized and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811008075

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